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Figure 1.
ML tree and colony of Annulohypoxylon stygium (PMEF05), a fungal endophyte of the tropical plant, Pandanus simplex.
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Figure 2.
Structure of 8-methoxynaphthol produced by the Annulohypoxylon stygium (PMEF05) from Pandanus simplex.
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Position 8-methoxynapthol, δH
measured at 400 MHz, CDCl38-methoxy-naphthol, δH
measured at 300 MHz, CDCl3[18]8-methoxynapthol, δc
measured at 100 MHz, CDCl38-methoxy-naphthol, δC
measured at 75 MHz, CDCl3[18]1 − − 154.7 154.6 2 7.33 (1H, m) 7.32 (1H, m) 118.9 118.0 3 7.36 (1H, m) 7.36 (1H, m) 125.6 125.8 4 7.42 (1H, d, J = 8.28 Hz) 7.44 (1H, m) 121.9 121.9 4a − − 136.9 136.9 5 7.29 (1H, dd, J = 7.80, 1.54 Hz) 7.29 (1H, m) 127.8 127.8 6 6.78 (1H, t, J = 7.80 Hz) 6.78 (1H, m) 110.5 110.6 7 6.88 (1H, dd, J = 7.80, 1.54 Hz) 6.93 (1H, m) 103.9 104.0 8 − − 156.3 156.3 8a − − 115.2 115.2 -CH3 4.06 (3H, s) 4.04 (3H, s) 56.2 56.2 -OH 9.35 (1H, s) 9.37 (1H, s) − − s: singlet; d: doublet; dd: doublet of a doublet; m: multiplet Table 1.
Comparison of 1H and 13C NMR data with literature data.
Figures
(2)
Tables
(1)