doi:10.48130/aee-0025-0014

[1]

Hriciková S, Kožárová I, Hudáková N, Reitznerová A, Nagy J, et al. 2023. Humic substances as a versatile intermediary. Life 13(4):858

doi: 10.3390/life13040858

[2]

Qiao H, Liu Z, Peng X, Xian H, Cheng K, et al. 2024. Significance of humic matters-soil mineral interactions for environmental remediation: a review. Chemosphere 365:143356

doi: 10.1016/j.chemosphere.2024.143356

[3]

Zhu X, Liu J, Li L, Zhen G, Lu X, et al. 2023. Prospects for humic acids treatment and recovery in wastewater: a review. Chemosphere 312:137193

doi: 10.1016/j.chemosphere.2022.137193

[4]

Santamaría-Fernández R, Cave MR, Hill SJ. 2003. The effect of humic acids on the sequential extraction of metals in soils and sediments using ICP-AES and chemometric analysis. Journal of Environmental Monitoring 5(6):929−934

doi: 10.1039/b306865j

[5]

Khurana P, Pulicharla R, Brar SK. 2024. Occurrence of imipenem in natural water: effect of humic acid on its stability and transformation. Science of The Total Environment 927:177846

doi: 10.1016/j.scitotenv.2024.177846

[6]

Lin Q, Luo A, Yu C, Chen K, Hamid Y, et al. 2024. Insights into the role of endogenous humic acid on antibiotics bioadsorption process in wastewater: mechanisms and potential implications. Journal of Water Process Engineering 64:105606

doi: 10.1016/j.jwpe.2024.105606

[7]

Yang C, Lai J, Li S, Wang J, Yang L, et al. 2024. Insight into the humic acid/antibiotic complexation for boosting tetracycline degradation by heterogeneous persulfate activation. Journal of Environmental Chemical Engineering 12(1):111712

doi: 10.1016/j.jece.2023.111712

[8]

Mzinyathi M, Muthuraj V, Ajala EO, Kakavandi B, Janse van Rensburg SJ, et al. 2025. Chlorine dioxide drinking water pre-oxidation and disinfection: a review of its effectiveness, mechanisms, and disinfection by-products. Desalination and Water Treatment 323:101340

doi: 10.1016/j.dwt.2025.101340

[9]

Nguyen HVM, Lim HB, Hur J, Shin HS. 2026. Hydrophobic neutral dissolved organic matter: first insights into compositional changes and formation of disinfection by-products induced by rainfall and degradation. Journal of Environmental Sciences 161:307−319

doi: 10.1016/j.jes.2025.08.022

[10]

Wang Q, Luo W, Huang K, Li H, Xu Q. 2025. Unveiling the impact of initial pH on humic acid degradation using ultraviolet light-activated peroxydisulfate in landfill leachate treatment. Journal of Environmental Chemical Engineering 13(5):119062

doi: 10.1016/j.jece.2025.119062

[11]

Verma Y, Sharma G, Iqbal J, Naushad M, Lai CW, et al. 2024. Recent advances in transition metal-based photocatalytic heterojunctions for algal inhibition and water disinfection: a review. Materials Today Sustainability 28:101041

doi: 10.1016/j.mtsust.2024.101041

[12]

Ma J, Ding N, Liu H. 2023. Research progress in photocatalytic activated persulfate degradation of antibiotics by bismuth-based photocatalysts. Separation and Purification Technology 324:124628

doi: 10.1016/j.seppur.2023.124628

[13]

Yaah VBK, Quimbayo JSM, Ahmadi S, Lempelto A, Sliz R, et al. 2025. One-pot co-precipitation of enhanced visible light active BiOCl based photocatalysts: characterization, mechanism and DFT modelling. Inorganic Chemistry Communications 182(3):115699

doi: 10.1016/j.inoche.2025.115699

[14]

Anwar S, Aslam Z, Aslam U, Mehmood U, Rana AG, et al. 2026. Advances and challenges in photocatalytic water splitting: recent developments and trends. Fuel 404(B):136280

doi: 10.1016/j.fuel.2025.136280

[15]

Cao M, Xu P, Tian K, Shi F, Zheng Q, et al. 2023. Recent advances in microwave-enhanced advanced oxidation processes (MAOPs) for environmental remediation: a review. Chemical Engineering Journal 471:144208

doi: 10.1016/j.cej.2023.144208

[16]

Hassani A, Pourshirband N, Sayyar Z, Eghbali P. 2025. Fenton and Fenton-like-based advanced oxidation processes. In Innovative and Hybrid Advanced Oxidation Processes for Water Treatment, ed. Hamdaoui O. Amsterdam: Elsevier. pp. 171−203 doi: 10.1016/B978-0-443-14100-3.00006-5

[17]

Li S, Zhang T, Zheng H, Dong X, Leong YK, et al. 2024. Advances and challenges in the removal of organic pollutants via sulfate radical-based advanced oxidation processes by Fe-based metal-organic frameworks: a review. Science of The Total Environment 926:171885

doi: 10.1016/j.scitotenv.2024.171885

[18]

Wang L, Tang Y, Wang P, Fu Y, Xu C, et al. 2025. Radical generation in thermally activated peroxydisulfate process with temperature threshold as low as 45 °C. Chemical Engineering Journal 526:171071

doi: 10.1016/j.cej.2025.171071

[19]

Zhang J, Li Z, Lei Q, Zhong D, Ke Y, et al. 2023. Significantly activated persulfate by novel carbon quantum dots-modified N-BiOCl for complete degradation of bisphenol-a under visible light irradiation. Science of The Total Environment 870:161804

doi: 10.1016/j.scitotenv.2023.161804

[20]

Pu C, Lu G, Qi H, Isaev AB, Zhu M. 2023. Enhanced persulfate activation process by magnetically separable catalysts for water purification: a review. Chinese Journal of Structural Chemistry 42(6):100093

doi: 10.1016/j.cjsc.2023.100093

[21]

Wang W, Zhou S, Zhu Y, Li W. 2025. A g-C₃N₄/BiOI heterojunction activated persulfate (PDS) for photocatalytic degradation of tetracycline in water/wastewater. Chemical Engineering Science 315:121881

doi: 10.1016/j.ces.2025.121881

[22]

Wang J, Chang X, Zhao Y, Xu H, He G, et al. 2022. A novel Bi₂WO₆/BiOBr/RGO photocatalyst for enhanced degradation of ciprofloxacin under visible light irradiation: performance, mechanism and toxicity evaluation. Diamond and Related Materials 128:109274

doi: 10.1016/j.diamond.2022.109274

[23]

Naderi A, Sagadevan S, Rezaei Kalantary R, Kakavandi B, Pelalak R, et al. 2026. Heterogeneous sulfate radical-based advanced oxidation process for the efficient pharmaceutical wastewater treatment: performance, practicability, and mechanism. Journal of Colloid and Interface Science 703:139106

doi: 10.1016/j.jcis.2025.139106

[24]

Ouyang L, Wang H, Duan L, Zhang J, Jiang S, et al. 2025. Synergistic photocatalytic degradation of tetracycline by Fe(II)/PMS and g-C₃N₅/BiVO₄ S-scheme heterojunction: mechanism and performance. Diamond and Related Materials 158:112640

doi: 10.1016/j.diamond.2025.112640

[25]

Alhammadi S, Kang S, Ryu DG, Mady AH, Azhar MHA, et al. 2024. Magnesium incorporation-mediated formation of oxygen vacancies in zinc ferrite for PMS activation toward effective photocatalytic 4-nitrophenol degradation. Applied Surface Science 677:161064

doi: 10.1016/j.apsusc.2024.161064

[26]

Hassani A, Varank G, Eghbali P, Can-Güven E, Guvenc SY, et al. 2025. Ultrasound-assisted oxidants for the degradation of organic pollutants: a state-of-the-art mechanistic review. Journal of Environmental Chemical Engineering 13(3):116682

doi: 10.1016/j.jece.2025.116682

[27]

Xu Z, Zhang C, Zhang Y, Gu Y, An Y. 2022. BiOCl-based photocatalysts: synthesis methods, structure, property, application, and perspective. Inorganic Chemistry Communications 138:109277

doi: 10.1016/j.inoche.2022.109277

[28]

Xie K, Xu S, Xu K, Hao W, Wang J, et al. 2023. BiOCl Heterojunction photocatalyst: construction, photocatalytic performance, and applications. Chemosphere 317:137823

doi: 10.1016/j.chemosphere.2023.137823

[29]

Yang C, Rong Q, Shi F, Cao M, Li G, et al. 2024. Rationally designed S-scheme heterojunction of BiOCl/g-C₃N₄ for photodegradation of sulfamerazine: mechanism insights, degradation pathways and DFT calculation. Chinese Chemical Letters 35(12):109767

doi: 10.1016/j.cclet.2024.109767

[30]

Tian W, Chen S, Zhang H, Wang H, Wang S. 2022. Sulfate radical-based advanced oxidation processes for water decontamination using biomass-derived carbon as catalysts. Current Opinion in Chemical Engineering 37:100838

doi: 10.1016/j.coche.2022.100838

[31]

Li X, Jie B, Lin H, Deng Z, Qian J, et al. 2022. Application of sulfate radicals-based advanced oxidation technology in degradation of trace organic contaminants (TrOCs): recent advances and prospects. Journal of Environmental Management 308:114664

doi: 10.1016/j.jenvman.2022.114664

[32]

Tian Y, Chu M, Yang J, Yao S, Li S. 2025. Advances in single/dual-atom catalysts for activating persulfate applied to organic pollutant degradation: the critical role of active site configuration. Resources Chemicals and Materials 2025:In press, journal pre-proof

doi: 10.1016/j.recm.2025.100166

[33]

Yu CB, Xu C, He L, Huang WY, Yang K, et al. 2025. Trigger efficient peroxydisulfate-assisted photocatalysis by S-scheme Co₃O₄/BiOCl heterojunctions: Vital roles of Co²⁺/Co³⁺ redox centers and oxygen vacancies. Journal of Environmental Chemical Engineering 13(6):119195

doi: 10.1016/j.jece.2025.119195

[34]

Li G, Yang C, Yang Q, Zheng Q, Li M, et al. 2026. A magnetically recyclable CoFe₂O₄/BiOBr S-scheme heterojunction for efficient photocatalytic degradation of diuron: performance, durability and mechanism exploration. Chinese Chemical Letters 37(1):111207

doi: 10.1016/j.cclet.2025.111207

[35]

Ma C, Mi X, Li P, He Z, Wang H. 2024. Photo-assisted oxygen-rich vacancy copper oxide catalyst to activate peroxymonosulfate (PMS) for efficient degradation of fulvic acid. Journal of Water Process Engineering 66:106060

doi: 10.1016/j.jwpe.2024.106060

[36]

Valenti-Quiroga M, Cabrera-Codony A, Emiliano P, Valero F, Monclús H, et al. 2024. In-depth analysis of natural organic matter fractions in drinking water treatment performance: fate and role of humic substances in trihalomethanes formation potential. Science of The Total Environment 954:176600

doi: 10.1016/j.scitotenv.2024.176600

[37]

Wu J, Zhao L, Gao X, Li Y. 2025. Multiscale structural regulation of Two-Dimensional materials for photocatalytic reduction of CO₂. Progress in Materials Science 148:101386

doi: 10.1016/j.pmatsci.2024.101386

[38]

He Q, Gao K, Ding P, Zhang L, Yang J, et al. 2025. Bimetallic cocatalyst for synergistic enhancement of Bi₄TaO₈Cl/Ti₃C₂−MXene@PtPd Ohm junctions photocatalytic hydrogen evolution performance. Separation and Purification Technology 379(3):135086

doi: 10.1016/j.seppur.2025.135086

[39]

Sharma G, Kumar A, Sharma S, Naushad M, Vo DVN, et al. 2022. Visible-light driven dual heterojunction formed between g-C₃N₄/BiOCl@MXene-Ti₃C₂ for the effective degradation of tetracycline. Environmental Pollution 308:119597

doi: 10.1016/j.envpol.2022.119597

[40]

Chen Z, Ma Y, Chen W, Tang Y, Li L, et al. 2023. Enhanced photocatalytic degradation of ciprofloxacin by heterostructured BiOCl/Ti₃C₂T_x MXene nanocomposites. Journal of Alloys and Compounds 950:169797

doi: 10.1016/j.jallcom.2023.169797

[41]

Ding T, Hu Y, Nie Z, Zheng M, Huang Y. 2025. Construction of nitrogen-doped graphene/BiOCl Schottky heterojunction for efficient photocatalytic degradation and CO₂ reduction. Environmental Research 264(1):120315

doi: 10.1016/j.envres.2024.120315

[42]

Cao M, Xu P, Shi F, Li G, Zhang G, et al. 2024. Ultra-Fast atrazine degradation through synergistic enhancement: exploring the synergistic mechanism of CoFe₂O₄/MXene and thermal on peroxymonosulfate activation. Chemical Engineering Journal 497:154388

doi: 10.1016/j.cej.2024.154388

[43]

Cheng X, Liao J, Xue Y, Lin Q, Yang Z, et al. 2022. Ultrahigh-flux and self-cleaning composite membrane based on BiOCl-PPy modified MXene nanosheets for contaminants removal from wastewater. Journal of Membrane Science 644:120188

doi: 10.1016/j.memsci.2021.120188

[44]

Khan S, Ahmad W, Akhtar N, Shah R, Ali A, et al. 2025. Cutting-edge research progress in synthesis and applications of MXene-based nanocomposites for water purification: a comprehensive review. Journal of Environmental Chemical Engineering 13(6):119941

doi: 10.1016/j.jece.2025.119941

[45]

Bi F, Jiang Z, Wang M, Lin Q, Liu X, et al. 2025. Enhanced remediation of cadmium-contaminated farmland by smooth vetch (Vicia villosa var.) coupled with phosphorus/sulfur co-doped biochar: synergetic performance and mechanism. Journal of Cleaner Production 496:144986

doi: 10.1016/j.jclepro.2025.144986

[46]

Mu F, Dai B, Dai C, Chu X, Xu J, et al. 2025. Novel 2D/1D MXene/Bi₅O₇I Schottky junction for photocatalytic degradation of bisphenol AF by peroxymonosulfate-assisted photocatalysis. Chinese Chemical Letters 2025:In press, journal pre-proof

doi: 10.1016/j.cclet.2025.111866

[47]

Xia L, Zhang K, Wang X, Guo Q, Wu Y, et al. 2023. 0D/2D Schottky junction synergies with 2D/2D S-scheme heterojunction strategy to achieve uniform separation of carriers in 0D/2D/2D quasi CNQDs/TCN/ZnIn₂S₄ towards photocatalytic remediating petroleum hydrocarbons polluted marine. Applied Catalysis B: Environmental 325:122387

doi: 10.1016/j.apcatb.2023.122387

[48]

Li H, Wang C, Li X, Zhang L, Wang Z. 2023. MXene-induced electronic structure modulation in BiOCl for boosting peroxymonosulfate activation under visible light: a combined experimental and DFT study. Environmental Science & Technology 57:11837−11847

doi: 10.1021/acs.est.3c02178

[49]

Wang Q, Yu M, Xu W, Li D, Lin X, et al. 2025. Photo-generation of hole dominated selective degradation of hydrophobic organic pollutants with tetracyanoquinodimethane (TCNQ)-modified BiOIO₃ catalyst. Chemical Engineering Journal 504:159036

doi: 10.1016/j.cej.2024.159036

[50]

Jin L, You S, Ren N, Liu Y. 2023. Selective activation of peroxymonosulfate to singlet oxygen by engineering oxygen vacancy defects in Ti₃CNT_X MXene for effective removal of micropollutants in water. Fundamental Research 3(5):770−776

doi: 10.1016/j.fmre.2022.03.005

[51]

Zhong KQ, Zhang HC, Xie DH, Guo PC, Zhang X, et al. 2025. Boosting carbonate radicals production to enhance photocatalytic Degradation of micropollutants. Water Research 287(B):124441

doi: 10.1016/j.watres.2025.124441

[52]

Liu J, Yuan X, Dong H, Sans C. 2025. Progress in MnO₂/MnO₂-based materials catalytic ozonation process for water and wastewater treatment. Journal of Environmental Management 383:125493

doi: 10.1016/j.jenvman.2025.125493

[53]

Wang W, Zhang S, Cui Z, Gao F, Tai Y, et al. 2025. Enhanced photocatalytic ozonation of bisphenol A using Ce doped Bi-MOF derived oxygen-rich vacancies Bi₂O₃/CeO₂. Separation and Purification Technology 364:132350

doi: 10.1016/j.seppur.2025.132350

[54]

Zhang Z, Lin J, Liu J, Li L, Zhuang W, et al. 2025. Effect of Cl⁻ on activated peroxymonosulfate based advanced oxidation process: transformation of radicals and mechanism of singlet oxygen generation. Separation and Purification Technology 367:132821

doi: 10.1016/j.seppur.2025.132821

[55]

Ye J, Ren M, Qian J, Li X, Chen Q. 2025. Advances in graphene quantum dots-based photocatalysts for enhanced charge transfer in photocatalytic reactions. Chinese Chemical Letters 36(9):110857

doi: 10.1016/j.cclet.2025.110857

[56]

Singh A, Dhau J, Kumar R, Badru R, Singh P, et al. 2024. Tailored carbon materials (TCM) for enhancing photocatalytic degradation of polyaromatic hydrocarbons. Progress in Materials Science 144:101289

doi: 10.1016/j.pmatsci.2024.101289

[57]

Ruiz-Castillo AL, Hinojosa-Reyes M, Camposeco R, Hinojosa-Reyes L. 2026. Advances in Bi₂O₃-based photocatalysts: a review on synergistic modifications and wastewater treatment applications. Inorganic Chemistry Communications 183(1):115730

doi: 10.1016/j.inoche.2025.115730

[58]

Lgaz H, Lee HS, Boukhlifi F, Messali M. 2026. Tetrabromobisphenol A (TBBPA) remediation: state-of-the-art mechanistic insights, innovative technologies, and sustainable management approaches. Separation and Purification Technology 382(3):135905

doi: 10.1016/j.seppur.2025.135905

[59]

Orimolade BO, Peleyeju MG, Yusuf TL. 2026. A comprehensive review on bismuth-based ternary heterojunctions in photocatalytic wastewater treatment. Journal of Environmental Management 397:128319

doi: 10.1016/j.jenvman.2025.128319

[60]

Amani AM, Abbasi M, Najdian A, Mohamadpour F, Kasaee SR, et al. 2025. MXene-based materials for enhanced water quality: advances in remediation strategies. Ecotoxicology and Environmental Safety 291:117817

doi: 10.1016/j.ecoenv.2025.117817

[61]

Erdem NG, Simsek EB. 2025. Engineering MXene based MWO₄ (M = Cu, Ni, Co) catalysts for dual-functional photocatalysis: Insights into wastewater remediation and hydrogen production. Surfaces and Interfaces 75:107786

doi: 10.1016/j.surfin.2025.107786

[62]

Liu Y, Wang P, Yin C, Xu C, Kang X, et al. 2025. Strategy for enhancing the degradation of tetracycline - a typical refractory antibiotic by Z-type heterojunction g-C₃N₅/BiOCl under visible light: electron capture effect of PDS. Journal of Environmental Chemical Engineering 13(2):115565

doi: 10.1016/j.jece.2025.115565

[63]

Kaur M, Hait P, Basu S. 2025. Flower-like NiAl-LDH/BiVO₄ Z-scheme photocatalysts for sunlight-driven degradation of azo dye: performance and mechanistic insights. RSC Advances 15(44):37166−37182

doi: 10.1039/d5ra06146f

[64]

Zhang H, Tian L, Han J, Wei Z, Wu Z, wt al. 2024. Insights into the PMS activation towards phenol removal mechanism by a Ti₃C₂-MXene doped BiVO₄ photocatalyst. Colloids and Surfaces A: Physicochemical and Engineering Aspects 698:134561

doi: 10.1016/j.colsurfa.2024.134561

[65]

Lin L, Xie D, Xu L, Huang Y, Qing XD, et al. 2023. One-step synthesis of floatable BiOCl/BiOBr@FACs enriched in oxygen vacancies for improved photocatalytic activity via peroxymonosulfate activation. Colloids and Surfaces A: Physicochemical and Engineering Aspects 676:132165

doi: 10.1016/j.colsurfa.2023.132165

[66]

Mu FH, Yang H, Xu SP, Chu XZ, Dai BL, et al. 2025. Peroxymonosulfate-assisted layered MXene/flower-like C-doped SnS₂ Schottky junction photocatalyst for ciprofloxacin effective degradation. Journal of Alloys and Compounds 1039:183354

doi: 10.1016/j.jallcom.2025.183354

[67]

Shen T, Wang P, Shi F, Xu P, Zhang G. 2024. Metal foam-based functional materials application in advanced oxidation and reduction processes for water remediation: design, mechanisms, and prospects. Chemical Engineering Journal 500:156825

doi: 10.1016/j.cej.2024.156825

[68]

Grzegórska A, Ofoegbu JC, Cervera-Gabalda L, Gómez-Polo C, Sannino D, et al. 2023. Magnetically recyclable TiO₂/MXene/MnFe₂O₄ photocatalyst for enhanced peroxymonosulphate-assisted photocatalytic degradation of carbamazepine and ibuprofen under simulated solar light. Journal of Environmental Chemical Engineering 11(5):110660

doi: 10.1016/j.jece.2023.110660

[69]

Qu JH, Wang JY, Li ZR, Wang JC, Liu YT, et al. 2025. Surfactant-Triggered Alkyl-like Radical Formation in Anaerobic Thermally Activated Persulfate System for Deep Removal of Highly Chlorinated Contaminants. Environmental Science & Technology 59(50):27730−27739

doi: 10.1021/acs.est.5c09101

[70]

Ye F, Wang JR, Ding Y, Bai JW, Shi Y, et al. 2025. Photoswitching-modulated interfacial electron transfer in single-atom Co-TiO₂ for enhanced pollutant mineralization in persulfate-based AOPs. Environmental Science & Technology 59(33):17869−17880

doi: 10.1021/acs.est.5c04734

[71]

Xiao T, Hou JW, Zhang SX, Liu DP, Gao HJ, et al. 2025. Two-Dimensional Heterospectral Correlation Analysis Elucidates Photodegradation Pathways of Riverine Dissolved Organic Matter Using Excitation–Emission Matrix and Ultraviolet Spectroscopy. Analytical Chemistry 97(30):16346−16354

doi: 10.1021/acs.analchem.5c01963

[72]

Wu W, Gao Y, Zhang J, Li L, Li Y, et al. 2024. Humic acid removal by persulfate activated with UV combined with magnetic ion exchange resin: performance and mechanism. The Chinese Journal of Process Engineering 24(5):566−579 (in Chinese)

doi: 10.12034/j.issn.1009-606X.223268